FABRICATION OF CAST AA5056 ALLOY-BASED COMPOSITES REINFORCED WITH BN, ZrO2 AND Si3N4
DOI:
https://doi.org/10.15407/plit2026.02.064Keywords:
AA5056 alloy, metal matrix composite, melt stiring, boron nitride, zirconia, silicon nitride, microstructure, mechanical properties, fluidity, porosityAbstract
Cast aluminum matrix composites (MMCs) produced by stir casting are of considerable interest due to their technological simplicity, relatively low cost, and the possibility of scalable manufacturing of components with balanced mechanical and casting properties. For Al—Mg alloys, particularly AA5056, the elevated magnesium content provides favorable conditions for improved wettability of dispersed particles and enables the implementation of dispersion and structural strengthening mechanisms. This study presents a comparative investigation of the influence of three types of reinforcing phases BN, ZrO2+BN, and Si3N4 on the formation of microstructure, porosity, fluidity, and mechanical properties of cast AA5056-based composites produced under identical stir-casting conditions. It is shown that the introduction of 2 wt.% dispersed particles into the melt leads to significantly different effects, governed both by the barrier action of particles on dendrite growth and by possible interfacial interactions. The most pronounced positive effect is observed for boron nitride: significant grain refinement, a more uniform distribution of alloying elements within the microvolume, and the formation of a more homogeneous structure are achieved. This is accompanied by a simultaneous increase in ultimate tensile strength and ductility, indicating an effective combination of strengthening mechanisms without brittle failure. The ZrO2+BN hybrid system exhibits less pronounced structural changes, with partial retention of dendritic morphology and particle agglomeration, which limits the efficiency of structural modification. At the same time, this composition demonstrates a compromise between strength, ductility, and fluidity, which is important for cast product manufacturing. The addition of Si3N4 results in increased strength due to grain refinement and possible local interfacial reactions; however, it is accompanied by a decrease in ductility due to stress concentration and the probable formation of brittle interaction products, such as interfacial nitride and silicide phases. As a result, the governing relationships between structure formation and property evolution in cast AA5056-based MMCs depending on the nature of the reinforcing phase have been established. They include grain-boundary strengthening and reduced microsegregation for BN, structural heterogeneity for the hybrid system, and possible interfacial reactions for Si3N4. The obtained results can be used for optimization of composition and processing parameters to achieve the required balance between mechanical and casting properties of the materials.
References
Kumar, D., Angra, S., & Singh, S. (2022). Mechanical properties and wear behaviour of stir cast aluminum metal matrix composite:A review. International Journal of Engineering, 35(4), 794—801. https://doi.org/10.5829/ije.2022.35.04a.19
Likhatskyi, R. F., Voron, M. M., Narivskii, A. V., Tverdokhvalov, V. O., Likhatskyi, I. F., & Matviets, E. O. (2025). Aluminum matrix composites based on casting aluminum alloys with oxides and carbides. Casting Processes, 159(1), 48-64. https://doi.org/10.15407/plit2025.01.048
Sangghaleh, A., & Halali, M. (2009). Effect of magnesium addition on the wetting of alumina by aluminium. Applied Surface Science, 255(19), 8202—8206. https://doi.org/10.1016/j.apsusc.2009.05.044
Saikrupa, C., Chandra Mohan Reddy, G., & Venkatesh, S. (2021). Aluminium metal matrix composites and effect of reinforcements – A Review. IOP Conference Series: Materials Science and Engineering, 1057(1), 012098. https://doi.org/10.1088/1757-899x/1057/1/012098
Likhatskyi, R., Voron, M., Narivskyi, A., Tverdokhvalov, V., & Matviiets, Y. (2025). Investigation of the fabrication of BN-reinforced pure aluminum composites by casting processe. New Materials and Technologies in Metallurgy and Mechanical Engineering, (3), 20—26. https://doi.org/10.15588/1607-6885-2025-3-3
Nemutlu, B., Kahraman, O., Demirel, K. B., Erkul, I., Cicek, M., Sahin, H., Dizdar, K. C., & Dispinar, D. (2023). Processing of boron nitride nanotubes reinforced aluminum matrix composite. Archives of Foundry Engineering, 2022(2), 5—10. https://doi.org/10.24425/afe.2022.140220
Abdulkader, N. J., Abass, M. A., Alkhafaji, M. M., & Jassim, G. (2025). Processing and mechanical properties of AA6061 matrix composites reinforced with nano scaled boron nitride. Revue des composites et des matériaux avancés, 35(3), 593—600. https://doi.org/10.18280/rcma.350320
Jung, W. G., & Kwon, H. (2004). Fabrication of BN/Al(-Mg) metal matrix composite (MMC) by pressureless infiltration technique. Materials Science Forum, 449-452, 301-304. https://doi.org/10.4028/www.scientific.net/msf.449—452.301
Madhusudhan, M., Naveen, G. J., & Mahesha, K. (2017). Mechanical characterization of AA7068-ZrO2 reinforced metal matrix composites. Materials Today: Proceedings, 4(2), 3122-3130. https://doi.org/10.1016/j.matpr.2017.02.196
Prakash, J. U., Jebarose Juliyana, S., Salunkhe, S., Gawade, S. R., Nasr, E. S. A., & Kamrani, A. K. (2023). Mechanical characterization and microstructural analysis of stir-cast aluminum matrix composites (LM5/ZrO2). Crystals, 13(8), 1220. https://doi.org/10.3390/cryst13081220
Rashed, G., Sadawy, M., Kandil, A., Abd Elkarim, A., & Mohrez, W. (2021). Influence of ZrO2 particles on the tribological properties of AlMg5 alloy. Journal of Petroleum and Mining Engineering, 23(1), 95—103. https://doi.org/10.21608/jpme.2021.68312.1078
Rosales-Cadena, I., Falcon-Castrejon, R. A., Guardian-Tapia, R., Roman-Zubillaga, J. L., Gonzaga-Segura, S. R., Falcon-Franco, L. A., Martinez-Landeros, V. H., & Servin, R. (2025). The effect of ZrO2 addition and thermal treatment on the microstructure and mechanical properties of aluminum metal matrix composites (AMMCs). Materials, 18(19), 4507. https://doi.org/10.3390/ma18194507
Podrezov, Y. M., Gogaev, K. O., Voropaev, V. S., Yevych, Y. I., Korzhova, N. P., & Legka, T. M. (2021). The structure and properties of precipitation-strengthened composites produced from a cast alloy in the Al-Si-Mg system. Powder Metallurgy and Metal Ceramics, 60(7—8), 496−503. https://doi.org/10.1007/s11106-021-00261-x
Anbuchezhiyan, G., Mohan, B., Senthilkumar, N., & Pugazhenthi, R. (2021). Synthesis and characterization of silicon nitride reinforced Al-Mg-Zn alloy composites. Metals and Materials International, 27, 3058−3069. https://doi.org/10.1007/s12540-020-00906-3
Öztop, B., & Gürbüz, M. (2021). Investigation of mechanical properties of Si3N4 reinforced composites produced from aluminum waste. European Journal of Science and Technology, 28, 758−765. https://doi.org/10.31590/ejosat.1010738
Ramesh Kannan, C., Venkatesh, R., Vivekanandan, M., Phani Krishna, J., Manivannan, S., Rajkumar, S., & Vijayan, V. (2022). Synthesis and characterization of mechanical properties of AA8014 + Si3N4/ ZrO2 hybrid composites by stir casting process. Advances in Materials Science and Engineering, 2022, 1−11. https://doi.org/10.1155/2022/9150442
Arya, S. M., & Griffiths, W. D. (2023). Aluminum nitride in Al-Si-Mg alloy. Metallurgical and Materials Transactions B. https://doi.org/10.1007/s11663-023-02810-8
Moustafa, E. B., Djouider, F., Alhawsawi, A., Elmoujarkach, E., Banoqitah, E., & Mohamed, S. S. (2023). A comprehensive investigation of BN and VC reinforcements on the properties of FSP AA6061 composites. Lubricants, 11(12), 507. https://doi.org/10.3390/lubricants11120507
Juliyana, S. J., Prakash, J. U., Salunkhe, S., Hussein, H. M. A., & Gawade, S. R. (2022). Mechanical characterization and microstructural analysis of hybrid composites (LM5/ZrO2/Gr). Crystals, 12(9), 1207. https://doi.org/10.3390/cryst12091207
Raghavendra Rao, P. S., & Mohan, C. B. (2020). Study on mechanical performance of silicon nitride reinforced aluminium metal matrix composites. Materials Today: Proceedings, 33, 5534−5538. https://doi.org/10.1016/j.matpr.2020.03.495
Chahuan, N., Singh, S., Thethi, H. P., Ch, S., A, S. J., & Ahmed, R. (2024). Enhancing aluminum-based composite manufacturing: harnessing Si3N4 reinforcement via stir casting technique. E3S Web of Conferences, 507, 01038. https://doi.org/10.1051/e3sconf/202450701038
Yürektürk, Y., Şenyurt, B., Çeltik, C., Küçükelyas, B., & Akçamlı, N. (2025). Si3N4 reinforced Al-Si-Mg matrix composites: powder metallurgy fabrication, PEO coating and characterization. Applied Surface Science, 162622. https://doi.org/10.1016/j.apsusc.2025.162622
Zhang, C. F., Cao, W., Fan, T. X., & Zhang, D. (2007). Prediction of the effect of alloying elements on in-situ reaction in synthesizing (AlN+Mg2Si)/Mg composites. Key Engineering Materials, 351, 156−160. https://doi.org/10.4028/www.scientific.net/kem.351.156
Zhu, X., Yang, H., Dong, X., & Ji, S. (2018). The effects of varying Mg and Si levels on the microstructural inhomogeneity and eutectic Mg2Si morphology in die-cast Al−Mg-Si alloys. Journal of Materials Science, 54(7), 5773−5787. https://doi.org/10.1007/s10853-018-03198-6
Okayasu, M., & Takeuchi, S. (2017). Mechanical properties of cast Al-Mg5 alloy produced by heated mold continuous casting. International Journal of Metalcasting, 12(2), 298−306. https://doi.org/10.1007/s40962-017-0163-6
Kataria, M., & Mangal, S. K. (2018). Characterization of aluminium metal matrix composite fabricated by gas injection bottom pouring vacuum multi-stir casting process. Metallic materials, 56(4), 231−243. https://doi.org/10.4149/km_2018_4_231
Mohammadtaheri, M. (2012). A new metallographic technique for revealing grain boundaries in aluminum alloys. Metallography, microstructure, and analysis, 1(5), 224−226. https://doi.org/10.1007/s13632-012-0033-9
Kishore, R., Karthick, G., Vijayakumar, M. D., & Dhinakaran, V. (2019). Analysis of mechanical behaviour of natural filler and fiber based composite materials. International journal of recent technology and engineering, 8(1S2), 117−124.
Zare, M. A., Taghiabadi, R., & Ghoncheh, M. H. (2021). Effect of cooling rate on microstructure and mechanical properties of AA5056 Al-Mg alloy. International Journal of Metalcasting. https://doi.org/10.1007/s40962-021-00704-6





