THE EFFECT OF ALLOYING, MICROALLOYING AND MODIFICATION ON THE PROPERTIES OF WEAR-RESISTANT CHROME MANGANESE CAST IRON

Procesi littâ, 2025, Vol 3 (161), 52-61

Authors

DOI:

https://doi.org/10.15407/plit2025.03.052

Keywords:

wear-resistant cast iron, hydroabrasive wearing, alloying, microalloying, modification, chromium, manganese, titanium, rare earth metals, carbides

Abstract

The paper presents the results of a study of the influence of chemical composition on the wear resistance of high-alloy cast irons operating under conditions of waterjet wear. The expediency of using chromium-manganese cast irons as a material for the manufacture of cast parts for ash removal systems of thermal power plants is substantiated. The main attention is focused on the study of the influence of chromium, manganese, titanium, and rare earth metals on the structure, hardness, and wear resistance of cast irons. The optimum content of alloying elements such as chromium and manganese, which will ensure maximum wear resistance of the experimental cast iron, was determined. The influence of microalloying of high-alloyed chromium-manganese cast iron with titanium and modification with rare earth metals was determined. The influence of structural components and morphology of carbides on the performance properties of cast iron has been studied. It is shown that the most effective is the structure of cast iron with carbides of the (Cr,Fe)₇C₃ type, evenly distributed in a martensitic or hardened base, as well as stabilized residual austenite capable of hardening during wear. It has been established that the introduction of 18-20 % Cr and 3.5-4.5 % Mn increases the wear resistance of the experimental cast iron by 20-25 % compared to the reference wear-resistant Cr28Ni2 alloy. It has been established that microalloying with titanium in the range of 0.4-0.6 % can further increase the wear resistance of cast iron by 15-20 % due to the formation of dispersed hardening carbides and carbonitrides. The addition of rare earth metals in the amount of 0.2-0.4 % helps to purify the metal from non-metallic inclusions, change their morphology, and improve mechanical properties. The optimal composition of wear-resistant cast iron has been proposed, which is advisable to use for the manufacture of screw conveyors, knees of pulp pipelines, impellers, housings, and disks of baghouse pumps that operate in direct contact with the pulp and are subject to water-abrasive wear in ash removal systems. The results can be used to further improve cast products and various technologies for strengthening their working surfaces. 

Author Biographies

I. V. Lukianenko, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” (Kyiv, Ukraine)

PhD (Engin.), Associate Professor

B. V. Kyvgylo, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” (Kyiv, Ukraine)

Assistant

E. Н. Byba, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” (Kyiv, Ukraine)

PhD (Engin.), Associate Professor

M. M. Yamshynskyi, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” (Kyiv, Ukraine)

Dr. Sci (Engin), Professor, Head of Department

O. H. Kovalchuk, Khmelnytsky NPP (Netishyn, Khmelnytsky region, Ukraine)

PhD (Engin.), Engineer of general shop personnel of the chemical shop

References

Melent’ev, V. L. (1978). Zoloshlakovie materiali i zolootvali [Ash-slag materials and ash dumps]. Energiya.

Gavrilov, E. I. (1987). Toplivno-transportnoe khozyaistvo i zoloshlakoudalenie na TES [Fuel and transportation facilities and ash and slag removal at TPPs]. Energoatomizdat.

Lyutyi, V. A., Platonov, E. A., Fedorov, G. E., & Kuzmenko, A. E. (2001). Khromoalyuminievie stali dlya izgotovleniya zharostoikikh detalei teploenergooborudovaniya [Chromium-aluminum steels for manufacturing heat-resistant parts of thermal power equipment]. Liteinoe-proizvodstvo, (4), 13–15.

Zhuk, N. P. (1976). Kurs teorii korrozii i zashchiti metallov [Course on corrosion and metal protection]. Metallurgiya.

Gudremon, E. (1966). Spetsialnie stali [Special steels] (Vol. 1). Metallurgiya.

Yamshinskiy, M. M., Fedorov, G. E., Platonov, E. A., Kuzmenko, A. E., & Radchenko, K. S. (2009). Pidvyshchennia hidroabrazyvnoi znosostiikosti vysokolehovanoho biloho chavunu [Increasing the hydroabrasive wear resistance of high-alloyed white cast iron]. Naukovi visti Natsionalnoho tekhnichnoho universytetu “KPI”, (1), 22–32.

Netrebko, V. V. (2015). Vliyanie otzhiga na tverdost visokokhromistikh chugunov, legirovannikh Mn i Ni [Effect of annealing on hardness of high-chromium irons alloyed with Mn and Ni]. Novi materialy i tekhnolohii v metalurhii ta mashynobuduvanni, (2), 65–70.

Belikov, S. B., Netrebko, V. V., & Volchok, I. P. (2015). Optimizatsiya sostava i svoistv iznosostoikikh visokokhromistikh chugunov [Optimization of composition and properties of wear-resistant high-chromium cast irons]. Vysoki tekhnolohii v mashynobuduvanni, (1), 18–26.

Netrebko, V. V., & Volchok, I. P. (2015). Vliyanie legirovaniya i termicheskoi obrabotki na raspredelenie elementov i svoistva visokokhromistikh chugunov [Effect of alloying and heat treatment on element distribution and properties of high chromium cast irons]. Nauchnii vestnik DGMA, (3), 52–59.

Yamshinskiy, M. M., Radchenko, K. S., & Fedorov, G. E. (2011). Optimizatsiya khimicheskogo sostava iznosostoikikh visokolegirovannikh belikh chugunov [Optimization of chemical composition of wear-resistant high-alloyed white cast irons]. Metall i lite Ukraini, (1), 21–24.

Coronado, J. J. (2011). Effect of (Fe,Cr)7C3 carbide orientation on abrasion wear resistance and fracture toughness. Wear, 270(3–4), 287–293. https://doi.org/10.1016/j.wear.2010.11.009

Fu, H., Wu, X., Li, X., et al. (2009). Effect of TiC particle additions on structure and properties of hypereutectic high chromium cast iron. Journal of Materials Engineering and Performance, 18(8), 1109–1115. https://doi.org/10.1007/s11665-009-9435-1

Yamshinskiy, M. M., Radchenko, K. S., & Fedorov, G. E. (2011). Vliyanie mikrolegirovaniya i modifitsirovaniya na strukturu i svoistva iznosostoikogo khromomargantsevogo chuguna [Effect of microalloying and modification on structure and properties of wear-resistantchromium-manganese cast iron]. Visnyk DDMA, (4), 133–140.

Yamshinskiy, M. M., Fedorov, G. E., & Radchenko, K. S. (2018). Khromomargantsevie chuguni dlya raboti v ekstremalnikh usloviyakh [Chromium-manganese cast irons for extreme conditions]. Metall i lite Ukraini, (7–8), 76–83

Radchenko, K. S., Platonov, E. A., Yamshinskiy, M. M., & Fedorov, G. E. (2013). Vliyanie titana i redkozemelnikh metallov na strukturu iznosostoikogo visokokhromistogo chuguna [Influence of titanium and rare-earth metals on the structure of wear-resistant high-chromium cast iron]. Metallurgicheskaya i gornorudnaya promishlennost, (4), 40–42.

Ri, K. (2000). Kompleksno-legirovannie chuguni spetsialnogo naznacheniya [Complex-alloyed cast irons for special purposes]. Dalnauka.

Yamshinskiy, M. M., Fedorov, G. E., Radchenko, K. S., & Platonov, E. A. (2013). Sluzhebnie kharakteristiki mikrolegirovannikh i modifitsirovannikh belikh chugunov [Service characteristics of microalloyed and modified white cast irons]. Lite i Metallurgiya, (4), 29–35.

Radchenko, K. S., Yamshinskiy, M. M., Fedorov, G. E., & Platonov, E. A. (2014). Izotermichnyi stupinchastyi vidpal khromomarhantsevykh chavuniv [Isothermal step annealing of chromium-manganese cast irons]. Visnyk DDMA, (1), 218–223.

Yamshinskiy, M. M., Fedorov, G. E., & Radchenko, K. S. (2015). Optimizatsiya rezhimov smyagchayushchego otzhiga iznosostoikikh khromomargantsevikh chugunov dlya uluchsheniya ikh obrabativaemosti rezaniem [Optimization of modes of softening annealing ofwear-resistant chromium-manganese cast irons to improve their machinability by cutting]. Metall i lite Ukraini, (12), 26–32.

Published

26-08-2025

How to Cite

Lukianenko І. ., Kyvgylo Б., Byba Є. ., Yamshynskyi М. ., & Kovalchuk О. . (2025). THE EFFECT OF ALLOYING, MICROALLOYING AND MODIFICATION ON THE PROPERTIES OF WEAR-RESISTANT CHROME MANGANESE CAST IRON: Procesi littâ, 2025, Vol 3 (161), 52-61. Casting Processes, 161(3), 52–61. https://doi.org/10.15407/plit2025.03.052

Issue

Section

CRYSTALLIZATION AND STRUCTURE FORMATION OF ALLOYS

Most read articles by the same author(s)

1 2 > >>